基于TLSER关系预测POPs在PUF与空气中的分配系数

为开发一种简洁高效预测K_PA值的方法,本文收集了包含多氯联苯（PCBs）、苯类（Benzenes）、多环芳香烃（PAHs）和杀虫剂（Pesticides）等,共95种污染物在聚氨酯泡沫塑料（PUF）与空气中分配系数（K_PA）的实验值,基于理论线性溶解能关系（TLSER）,运用逐步多元线性回归（MLR）构建了预测K_PA值的模型.结果表明,模型的决定系数R_adj²为0.901,外部验证系数Q_ext²为0.748.TLSER模型有较好的拟合度、稳健性和预测能力,可以预测应用域内POPs在PUF和空气之间的分配系数.     

重庆地铁岩石隧道环境振动衰减规律

本文研究了重庆地铁岩石隧道环境振动衰减规律，并预测了重庆地铁振动的影响范围和程度。     

密度泛函方法预测二英类化合物(PCDD/Fs)的正辛醇/水分配系数

在B3LYP/6-31G水平上全优化计算了多氯代二苯并一对-二(噁)英和多氯代二苯并呋喃(PCDD/Fs)系列物的分子结构;基于得到的分子结构描述符,依据修正的线性溶解能理论,分别建立了PCDDs和PCDFs的正辛醇/水分配系数的定量结构-性质关系模型(R2分别为0.985和0.966),并用交叉验证法对模型进行了验证(q2分别为0.983和0.936),用t-检验对各变量进行了检验.检验结果表明,模型的预测能力优于AM1法、单苯环氯取代指数法和拓扑量子方法得出的模型.     

Parameters affecting partitioning of 6 PCB congeners in natural sediments

Polychlorinated biphenyls (PCBs) released by bottom sediments were determined by experiments in which the sediments were artificially resuspended using sediment contaminated with PCBs in a particle entrainment simulator (PES). Sediment cores, spikedwith PCBs, were collected from the Housatonic River in Connecticut and run in the PES at simulated shear stresses from 0 to 0.6 N m^-2. Experimental results from these simulations have shown that mean concentration of PCBs in thesolid phase for sites with high volatile organic carbon (VOC) were significantly greater than samples with low VOC; the reversewas true for the water phase. In addition, on a mass load basis,the amount of PCBs found in sediment increased when shear stresses were increased from 0 to 0.6 N m^-2, beyond which shear stress did not affect mass loads in the watercolumn. Partition coefficients (K _p) were determined from PESsediment and water data for the following congeners: PCB 28, PCB 52, PCB 101, PCB 138, PCB 153, PCB 180. K _p was determined to be inversely proportional to total suspended solids (TSS), butdirectly proportional to chlorine content of the congener. Because of the strong influence of TSS and VOC concentrations onK _p values, agitation of samples using a PES better simulatedreal environmental conditions when compared to jar studies where no agitation was employed. Therefore, a device like the PES is more appropriate in obtaining K _p that would be found underreal stream flow conditions when compared to the traditionalway of measuring K _p using the jar study technique.     

人工神经网络模拟芳基脲土壤吸附系数研究

对38种芳基脲类化合物的土壤吸附系数进行了定量结构－活性相关研究。利用量子化学的AM1方法提取化合物的结构参数，运用多元回归分析和人工神经网络对该化合物进行比较研究。研究结果表明，神经网络法所得结果优于多元回归分析结果，并对分析结果进行了吸附机理讨论。     

护耳器声衰减性能评价方法的分析研究

简要介绍了最新护耳器声衰减性能评价方法和评价量,利用其方法对美国现今使用的耳塞进行了计算。对本文所涉及的３种评价方法进行分析、比较和评述,并提出建议     

Taking advantage of storm and waste water retention basins as part of water use minimization in industrial sites

A methodology for water use minimization has been developed by the Clean Technology Network of Bahia over a 10 year period in joint cooperative programs with the chemical, petrochemical and copper metallurgy industries located in the largest Industrial Complex in Latin America, in Camaçari, Bahia, Brazil. The methodology comprises a set of tools including reconciled aqueous stream balances, database of aqueous streams; large scale training leading to the identification of water minimization alternatives in the processes, water reuse optimization approaches; geographical information systems as well as, consideration of the region's hydro and hydro-geological characteristics. The results of a study carried out to assess the possibility of using storm and wastewaters for industrial use is presented in this paper. The inorganic system is composed by three water reservoirs (basins) receiving stormwater contaminated with inorganic effluents, and occasionally with organics. These basins have been operated to control water flow inputs according to the capacity of the pumping outlet systems before their discharge to a submarine outfall. A mass balance was performed with historical updated data to assess water availability from the basins based on the daily volume variation and flow rate of inorganic effluent from 2001 to 2007. The study identified the possibility of recovering about 1140 m³/h of the overall 5400 m³/h consumed by the Industrial Complex at the moment. Organizational changes in the present effluent disposal and stormwater harvest systems will be required in order to maximize water recovery for industrial use.     

万宁地区近地面氯离子沉积速率的影响因素研究

目的 研究热带海洋大气环境中不同地貌下氯离子沉积速率的分布规律及主要影响因素。方法 通过挂片法采集万宁地区的氯离子沉积速率,并分析离海距离、地形地貌对氯离子沉积速率的影响,以及其与海水因素、自然环境因素间的相关性。结果 近海开阔区域氯离子沉积速率受离海距离和地貌的影响显著,在300 m处降低至90 m处的1/3左右,地貌的变化导致同一距离点处的氯离子沉积速率相差30倍。另外,高的海水有效波高、风速和东风占比使春季氯离子沉积速率高于夏季。结论 不同地貌下的氯离子沉积速率均与海水有效波高、风速间呈较强的正相关性。     

Synthesis and characterization of an ion exchanger based on tamarind kernel powder and its application for removal of some metal ions from industrial effluents

A resin synthesized from tamarind kernel powder possesses high selectivity for metal ions. Distribution coefficients for some metal ions has been determined by the batch method. The influence of pH on ion exchange capacity and K _d value of metal ions were studied. The resin has been characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, chemical composition and ion exchange capacity (IEC). The selectivity order is Pb²⁺?>?Cu²⁺?>?Fe²⁺?>?Zn²⁺?>?Ni²⁺. Removal of metal ions from the aqueous solution and from effluents of a steel mill has been studied.     

1,2,4,5-四氯苯 C 18 Empore TM 膜/水分配系数的研究

研究了1，2，4，5-四氯苯在C18膜／水相之间的分配规律。1，2，4，5-四氯苯在：25℃，80r／min条件下恒温震荡96h可达分配平衡，温度和盐度对1，2，4，5-四氯苯C18膜／水的分配过程影响很小，1，2，4，5-四氯苯C18膜／水分配平衡时间受溶液体积和容器容积的影响，但不受溶液中C18膜膜量的影响，推测脂溶性小于或接近1，2，4，5-四氯苯的有机污染物在恒温震荡条件下C18膜与水之间的分配96h可达到平衡。